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Transient emissions of a turbocharged three-litre V6 diesel engine fuelled by hydrogenated vegetable oil (HVO) blends were experimentally investigated and compared with transient emissions of diesel as reference. The transient emissions measurements were made by highly-dynamic emissions instrumentations including Cambustion HFR500, CLD500 and DMS500 particulate analyzer. The HVO blends used in this study were 30% and 60% of HVO in diesel by volume. The transient conditions were simulated by load increases over 5 s, 10 s and 20 s durations at a constant engine speed. The particulate, NO, HC concentrations were measured to investigate the mechanism of emission formation under such transient schedules. The results showed that as the load increased, NO concentrations initially had a small drop before dramatically increasing for all the fuels investigated which can be associated with the turbocharger lag during the load transient.

The purpose of this study is to improve the carbon monoxide (CO) and total hydrocarbons (THC) conversion efficiency of a diesel oxidation catalyst (DOC) by enhancing the monolith thermal behaviour through modification of the substrate cell density and wall thickness. The optimisation is based on catalyst properties (light off performance, conversion efficiency, pressure drop and mechanical durability). These properties were first estimated using theoretical equations derived from literature in order to select commercially available substrates for further modelling studies. The thermal behaviour and conversion efficiency of the selected catalysts under diesel exhaust gas conditions were numerically studied using data from an EU5 diesel engine operating a New European Driving Cycle (NEDC). This simulation was carried out on a commercial exhaust aftertreatment modelling program, AXISUITE. The predictions were compared to a reference coated 400/4 catalyst.

Research studies show that 2-methylfuran (MF) is a promising gasoline alternative regarding its positive effect on engine performance and emissions. Before using pure MF in spark ignition engines, it is more likely to be used in a low-level blended form in gasoline. An experimental research study was carried out to investigate the impacts of low-level MF content in gasoline (volumetric 10% MF in blend) on direct-injection spark-ignition (DISI) engine combustion behavior and emissions. The tests were conducted on a single-cylinder spray-guided DISI research engine at an engine speed of 1500 rpm under stoichiometric conditions. The engine loads of 3.5 ~ 8.5 bar IMEP were tested and gasoline-optimized spark timing was used. Furthermore, the effects of spark timing, exhaust gas recirculation (EGR) and valve overlap on NOx emissions were tested.

Exhaust Gas Fuel Reforming has potential to be used for on-board generation of hydrogen rich gas, reformate, and to act as an energy recovery system allowing the capture of waste exhaust heat. High exhaust gas temperature drives endothermic reforming reactions that convert hydrocarbon fuel into gaseous fuel when combined with exhaust gas over a catalyst - the result is an increase in overall fuel energy that is proportional to waste energy capture. The paper demonstrates how the combustion of reformate in a direct injection gasoline (GDI) engine via Reformed Exhaust Gas Recirculation (REGR) can be beneficial to engine performance and emissions. Bottled reformate was inducted into a single cylinder GDI engine at a range of engine loads to compare REGR to conventional EGR. The reformate composition was selected to approximate reformate produced by exhaust gas fuel reforming at typical gasoline engine exhaust temperatures.

For spark ignition (SI) engines, the optimum spark timing is crucial for maximum efficiency. However, as the spark timing is advanced, so the propensity to knock increases, thus compromising efficiency. One method to suppress knock is to use high octane fuel additives. However, the blend ratio of these additives cannot be varied on demand. Therefore, with the advent of aggressive downsizing, new knock mitigation techniques are required. Fortuitously, there are two well-known lower alcohols which exhibit attractive knock mitigation properties: ethanol and methanol. Both not only have high octane ratings, but also result in greater charge-cooling than with gasoline. In the current work, the authors have exploited these attractive properties with the dual-injection, or the dual-fuel concept (gasoline in PFI and fuel additive in DI) using pure ethanol and methanol.

Ethanol has long been regarded as the optimal gasoline-alternative biofuel for spark-ignition (SI) engines. It is used widely in Latin and North America and is increasingly accepted as an attractive option across Europe. Nevertheless, its low energy density requires a high rate of manufacture; in areas which are deficient of arable land, such rates might prove problematic. Therefore, fuels with higher calorific values, such as butanol or 2,5-dimethylfuran (DMF) deserve consideration; a similar yield to ethanol, in theory, would require much less land. This report addresses the suitability of DMF, to meet the needs as a biofuel substitute for gasoline in SI engines, using ethanol as the biofuel benchmark. Specific attention is given to the sensitivity of DMF to various engine control parameters: combustion phasing (ignition timing), injection timing, relative air-fuel ratio and valve timing (intake and exhaust).

The new fuel, 2, 5-dimenthylfuran, known as DMF, captured worldwide attention since the discovery of its new production method. As a potential bio-fuel, DMF is competitive to gasoline in many areas, such as energy density, combustion efficiency and emissions. However, little work has been performed on its unconventional combustion mode. In this work, high speed imaging and thermal investigation are carried out to study DMF and gasoline dual-injection on a single cylinder, direct injection spark ignition optical engine. This dual-injection strategy combines direct injection (DI) and port fuel injection (PFI) simultaneously which means two different fuels can blend in the cylinder with any ratio. It provides a flexible way to use bio-fuels with gasoline. DMF DI with gasoline PFI and ethanol DI with gasoline PFI are studied under different injection proportions (by volume) and IMEPs.

In this paper blends of diesel and gasoline (dieseline) fuelled Partially Premixed Compression Ignition (PPCI) combustion and the comparison to conventional diesel combustion is investigated. The tests are carried out using a light duty four cylinder Euro IV diesel engine. The engine condition is maintained at 1800 rpm, 52 Nm (equivalent IMEP around 4.3 bar). Different injection timings and different amounts of EGR are used to achieve the PPCI combustion. The results show that compared to the conventional diesel combustion, the smoke and NOx emissions can be reduced by more than 95% simultaneously with dieseline fuelled PPCI combustion. The particle number total concentration can be reduced by 90% as well as the mean diameter (from 54 nm for conventional diesel to 16 nm for G50 fuelled PPCI). The penalty is a slightly increased noise level and lower indicated efficiency, which is decreased from 40% to 38.5%.

In the automotive industry, engine downsizing has been widely accepted as an enabler to improving the fuel economy and reducing the CO₂ emissions. The Atkinson cycle is one of the key technologies. In this paper, the Atkinson cycle with different expansion ratios are compared and analyzed. The investigation is compared with the benchmark whose expansion and compression ratio are identical. The aim is to understand the inherent characteristics of the over-expansion and its effect on the engine performance and emissions. The simulation results show that, the Atkinson cycle produces higher efficiency due to over-expansion. The Atkinson cycle has higher internal EGR compared with the benchmark at equivalent conditions, which contributes to lower the NOx and CO emissions.

It is well known that direct injection (DI) is a technology enabler for stratified combustion in spark-ignition (SI) engines. At full load or wide-open throttle (WOT), partial charge stratification can suppress knock, enabling greater spark advance and increased torque. Such split-injection or double-pulse injection strategies are employed when using gasoline in DI (GDI). However, as the use of biofuels is set to increase, is this mode still beneficial? In the current study, the authors attempt to answer this question using two gasoline-alternative biofuels: firstly, ethanol; the widely used gasoline-alternative biofuel and secondly, 2,5-dimethylfuran (DMF); the new biofuel candidate. These results have been benchmarked against gasoline in a single-cylinder, spray-guided DISI research engine at WOT (λ = 1 and 1500 rpm). Firstly, single-pulse start of injection (SOI) timing sweeps were conducted with each fuel to find the highest volumetric efficiency and IMEP.

Two approaches were adopted to study soot oxidation by NO₂; firstly microreactor tests were performed on soot produced by a soot generator over a range of NO₂ concentrations and temperatures. This enabled measurement to be made under well-controlled conditions. Secondly, soot oxidation measurements were made on an engine bench to obtain data under more realistic, if less controlled, conditions. In the microreactor work NO₂ consumption by soot oxidation and the selectivity of the soot oxidation to CO and CO₂ were measured. The latter was found to vary only slightly with temperature and to be independent of NO₂ concentration. By modeling this data using a 1-dimensional model, rate equations for the soot-NO₂ reaction were determined. These were then tested against the engine data. The soot used in this study was characterized by thermogravimetric analysis, N₂ physisorption and transmission electron microscopy.

In earlier work we have shown that engine operation with oxygenated fuels (e.g., biodiesel) reduces the particulate matter (PM) emissions and extends the engine tolerance to exhaust gas recirculation (EGR) before it reaches smoke limited conditions. The same result has also been reported when high cetane number fuels such as gas-to-liquid (GTL) are used. A likely mechanism for engine-out particulate growth is the reintroduction of particle nuclei into the cylinder through EGR. These recirculated PM particles serve as sites for further condensation and accumulation promoting larger and greater number of particles. In order to further our understanding of EGR influence on total PM production, a diesel particulate filter (DPF) was integrated into the EGR loop. A PM reduction of approximately 50% (soot) was achieved with diesel fuel through filtered EGR, whilst still maintaining a significant NOX reduction.

Computational Fluid Dynamics (CFD) is used to simulate chemical reactions and transport phenomena occurring in a single channel of a honeycomb-type automotive catalytic converter under lean burn combustion. Microkinetic analysis is adopted to develop a detailed elementary reaction mechanism for propane oxidation on a silver catalyst. Activation energies are calculated based on the theory of the Unity Bond Index-Quadratic Exponential Potential (UBI-QEP) method. The order-of-magnitude of the pre-exponential factors is obtained from Transition State Theory (TST). Sensitivity analysis is applied to identify the important elementary steps and refine the pre-exponential factors of these reactions. These pre-exponential factors depend on inlet temperatures and propane concentration; therefore optimised pre-exponential factors are written in polynomial forms. The results of numerical simulations are validated by comparison with experimental data.

In this paper, the microscopic spray characteristics of diesel, Rapeseed Methyl Ester (RME) and Gas-to-Liquid (GTL) fuel, were studied at different injection pressures and measuring positions using Phase Doppler Anemometry (PDA) technique and the velocity development and size distributions of the fuel droplets were analysed in order to understand spray atomisation process. The injection pressures ranged from 80MPa to 150MPa, and the measuring position varied from 20mm to 70mm downstream the nozzle. It was found that the data rate is quite low in the near nozzle region and at high injection pressure. Sauter Mean Diameter (SMD) of all fuels obviously decreases when the injection pressure increases from 80MPa to 120MPa; but the injection pressure has little promotion on the axial velocity of droplets.

The use of accurate tire material properties is a major requirement for conducting a successful tire analysis using finite element method (FEM). Obtaining these material properties however poses a major challenge for tire modelers and researchers due to the complex nature of tire material and associated proprietary protections of constituent material properties by tire manufactures. In view of this limitation, a simple and effective procedure for generating tire materials data used in tire finite element analysis (FEA) is presented in this paper. All the tire test specimens were extracted from a tire product based on special considerations such as specimen dimension and shape, test standard, precondition of specimen and test condition for cords. The required material properties of tire rubber component, including hyperelasticity and viscoelasticity were obtained using simple uni-axial tension test.

The fuel reforming technology has been extensively investigated as a way to produce hydrogen on-board a vehicle that can be utilized in internal combustion engines, fuel cells and aftertreatment technologies. Maximization of H2 production in the reforming process can be achieved when there is optimized water (steam) addition for the different reforming temperatures. A way to increase the already available water quantity on-board a vehicle (i.e. exhaust gas water content) is by using emulsified fuel (e.g. water-diesel blend). This study presents the effect of an emulsified diesel fuel (a blend of water and diesel fuel with an organic surfactant to make the mixture stable) on combustion in conjunction with exhaust gas assisted fuel reforming on a compression ignition engine. No engine modification was required to carry out these tests. The emulsified diesel fuel consisted of about 80% (mass basis) of conventional ultra low sulphur diesel (ULSD) fuel and fixed water content.

Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.

The paper presents analysis of performance and emission characteristics of a common rail diesel engine operating with RME, with and without EGR. In both cases, the RME fuel was pre-heated in a heat exchanger to control its temperature before being pumped to the common rail. The studied parameters include the in-cylinder pressure history, rate of heat release, mass fraction burned, and exhaust emissions. The results show that when the fuel temperature increases and the engine is operated without EGR, the brake specific fuel consumption (bsfc) decreases, engine efficiency increases and NOx emission slightly decreases. However, when EGR is used while fuel temperature is increased, the bsfc and engine efficiency is independent of fuel temperature while NOx slightly increases.

Limits on the total future potential of biodiesel fuel due to the availability of raw materials mean that ambitious 20% fuel replacement targets will need to be met by the use of both first and next generation biodiesel fuels. The use of higher percentage biodiesel blends requires engine recalibration, as it affects engine performance, combustion patterns and emissions. Previous work has shown that the combustion of 50:50 blends of biodiesel fuels (first generation RME and next generation synthetic fuel) can give diesel fuel-like performance (i.e. in-cylinder pressure, fuel injection and heat release patterns). This means engine recalibration can be avoided, plus a reduction in all the regulated emissions. Using a 30% biodiesel blend (with different first and next generation proportions) mixed with Diesel may be a more realistic future fuel.

In this work, a detailed process for manufacturing 3D alumina composite microengine pistons is presented. A novel moulding process is developed for shaping alumina composites into accurate micrometer-sized parts with a combination of softlithography micromoulding techniques and colloidal ceramic powder process. Ultrathick SU-8 UV-lithography is used for making master moulds followed by mirror duplication of PDMS softmoulds. A preceramic coating resin (PCR) was used as the binder instead of the traditionally organic binders and the PCR turns into an additive to the composite after the sintering process. The sedimentation of Al2O3/acetone suspensions has been characterized with varying poly vinyl pyrrolidone (PVP) as a dispersant. Optimized PCR and curing conditions have been investigated in the soft moulding process, and prove successful in achieving dense and uniform microcomponents.